Solvent??and concentration??sensitive fluorescence of 2??(3, 4, 5, 6??tetrafluoro??2??hydroxyphenyl) benzoxazole

…, M Deguchi, S Yamaguchi, K Yamada…

Index: Tanaka; Deguchi; Yamaguchi; Yamada; Iwata Journal of Heterocyclic Chemistry, 2001 , vol. 38, # 1 p. 131 - 136

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Citation Number: 15

Abstract

Abstract 2-(3, 4, 5, 6-Tetrafluoro-2-hydroxyphenyl) benzoxazole (2) emits the long wavelength fluorescence around 500 nm in nonpolar solvent via the intramolecular proton transfer process in the excited state of 2 (enol-form) and also emits the intermediate wavelength fluorescence around 440 nm in polar solvent, which is assumed to originate from the excited state of 2 (anion). The ease of formation of 2 (anion), compared to 2-(2- ...