Electroorganic chemistry. 60. Electroorganic synthesis of enamides and enecarbamates and their utilization in organic synthesis

…, Y Matsumura, K Tsubata, Y Sugihara…

Index: Shono, Tatsuya; Matsumura, Yoshihiro; Tsubata, Kenji; Sugihara, Yoshihiro; Yamane, Shin-ichiro; et. al. Journal of the American Chemical Society, 1982 , vol. 104, # 24 p. 6697 - 6703

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Citation Number: 195

Abstract

Abstract: A variety of enecarbamates and enamides were synthesized from a-methoxy carbamates and a-methoxy amides prepared by anodic methoxylation of amine derivatives. Some new carbonxarbon bond-forming reactions and hydroxylation at the@ position of amines have been accomplished by using these enecarbamates and enamides as key intermediates. Also, new synthetic routes of nicotinaldehyde and pyrrole derivatives have ...

~82%

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