Synthesis

Nickel catalyzed electrochemical heteroarylation of activated olefins

S Condon, D Dupre, I Lachaise, JY Nédélec

Index: Condon, Sylvie; Dupre, Daniel; Lachaise, Isabelle; Nedelec, Jean-Yves Synthesis, 2002 , # 12 p. 1752 - 1758

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Abstract

Abstract Conjugate addition reaction of heteroaryl halides to activated olefins has been successfully achieved by nickel catalysis combined with the consumable anode procedure and provides access to various functionalized heteroaryl compounds with potential biological activity.

~72%

~80%

~30%

~31%

~15%

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Photochemical generation of aliphatic radicals from benzophe...

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