Bulletin of the Chemical Society of Japan

Allylation of quinones via photoinduced electron-transfer reactions from allylstannanes.

K Maruyama, H Imahori

Index: Maruyama, Kazuhiro; Imahori, Hiroshi Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 3 p. 816 - 825

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Citation Number: 16

Abstract

Photochemical reactions of quinones with allylstannanes provided four types of products: adducts of allyl group to the carbonyl oxygens of quinones, adducts of allyl group to the olefinic carbons, adducts of allyl group to the carbonyl carbons, and hydroquinones. An electron-transfer mechanism was confirmed by 1 H-CIDNP (Chemically Induced Dynamic Nuclear Polarization) method. This study suggests that a) photoinduced electron transfer ...