Synthesis and Characterization of (Z)??1??[2??(Tribenzylstannyl) vinyl]??1??cycloheptanol and its Benzylhalostannyl Derivatives

…, C Jia, P Liang, X Yang, H Chen

Index: Ren, Yujie; Jia, Cuiying; Liang, Peng; Yang, Xuefeng; Chen, Huilin Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 2003 , vol. 33, # 6 p. 1115 - 1123

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Citation Number: 2

Abstract

1??Ethynyl??1??cycloheptanol reacts with tribenzylstannylhydride,(C6H5CH2) 3SnH, and generates the corresponding (Z)??1??[2??(tribenzylstannyl) vinyl]??1??cycloheptanol. The product obtained reacts with one or two equivalents of halogen (I2, Br2 or ICl) to form the associated (Z)??1??[2??(dibenzylhalostannyl) vinyl]??1??cycloheptanol or (Z)??1??[2??(benzyldihalostannyl)?? vinyl]??1??cycloheptanol, respectively. All compounds were characterized by elemental ...