Fe??HCl: An Efficient Reagent for Deprotection of Oximes as well as Selective Oxidative Hydrolysis of Nitroalkenes and Nitroalkanes to Ketones

PK Pradhan, S Dey, P Jaisankar…

Index: Pradhan, Prasun K.; Dey, Sumit; Jaisankar, Parasuraman; Giri, Venkatachalam S. Synthetic Communications, 2005 , vol. 35, # 7 p. 913 - 922

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Citation Number: 29

Abstract

Abstract Fe??HCl mixture was found to selectively perform oxidative hydrolysis of the nitroalkenes 1a–j and nitroalkanes 2a–j to the ketones 3a–j. Also, the reagent was observed to deprotect the oximes 7a–j to carbonyl compounds 8a–j in excellent yields.