Journal of carbohydrate chemistry

Convenient Multigram Scale Glycosylations of Scented Alcohols Employing Phase??Transfer Reactions

L Kröger, J Thiem

Index: Kroeger, Lars; Thiem, Joachim Journal of Carbohydrate Chemistry, 2003 ,  vol. 22,  # 1  p. 9 - 24

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Citation Number: 26

Abstract

Various conditions for glycosylation (Koenigs–Knorr, Helferich, trichloroacetimidate, Fischer– Raske, phase??transfer methods) of 3??ethoxy??4??hydroxybenzaldehyde (ethyl vanillin), 3?? hydroxy??2??methyl??4??pyranone (maltol) and 2, 5??dimethyl??4??hydroxy??3 (2 H)??furanone (furaneol®) were evaluated, taking into account yields and ease of preparation (eg, utilized donor, catalyst, conditions). The best results were achieved employing phase transfer ...