Synthesis

Pseudohalogenation of phosphites

E Shi, C Pei

Index: Shi, Enxue; Pei, Chengxin Synthesis, 2004 , # 18 p. 2995 - 2998

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Citation Number: 13

Abstract

Abstract A new type of Atherton-Todd reaction for a convenient pseudohalogenation of phosphites has been developed. Direct azidation, cyanation, and thiocyanation of (RO) 2 P (O) H (R= Et, i-Bu, Ph) were accomplished readily with sodium pseudohalides in acetonitrile