ACS catalysis

Copper-catalyzed carboxylation of aryl iodides with carbon dioxide

H Tran-Vu, O Daugulis

Index: Tran-Vu, Hung; Daugulis, Olafs ACS Catalysis, 2013 , vol. 3, # 10 p. 2417 - 2420

Full Text: HTML

Citation Number: 25

Abstract

A method for carboxylation of aryl iodides with carbon dioxide has been developed. The reaction employs low loadings of copper iodide/N, N, N′, N′-tetramethylethylenediamine (TMEDA) or N, N′-dimethylethylenediamine (DMEDA) catalyst, 1 atm of CO2, dimethylsulfoxide (DMSO) or dimethylacetamide (DMA) solvent, and proceeds at 25–70° C. Good functional group tolerance is observed, with ester, bromide, chloride, fluoride, ether, ...

~83%

~68%

~63%

~61%

~74%

~52%

~57%

~61%

~79%

~54%

~41%

~44%

Lithium hypochlorite-clorox as a novel oxidative mixture for...

[Madler; Klucik; Soell; Brown; Liu; Berlin; Benbrook; Birckbichler; Nelson Organic Preparations and Procedures International, 1998 , vol. 30, # 2 p. 230 - 234]

Rhodium (I)-catalyzed carboxylation of aryl-and alkenylboron...

[Ukai, Kazutoshi; Aoki, Masao; Takaya, Jun; Iwasawa, Nobuharu Journal of the American Chemical Society, 2006 , vol. 128, # 27 p. 8706 - 8707]

Chromium-pillared clay as a catalyst for benzylic oxidation ...

[Choudary, Boyapati M.; Prasad, Annavajhula Durga; Bhuma, Vendantam; Swapna, Vinukonda Journal of Organic Chemistry, 1992 , vol. 57, # 22 p. 5841 - 5844]

An efficient approach for the deprotection of esters using i...

[Wei, Benmei; Zhang, Zhiyong; Dai, Zhiqun; Guan, Jintao Asian Journal of Chemistry, 2013 , vol. 25, # 11 p. 6404 - 6406]

A New Strategy for the Preparation of Terephthalic Acid by t...

[Advanced Synthesis and Catalysis, , vol. 343, # 2 p. 220 - 225]