Synlett

Heck reaction catalyzed by mesoporous SBA-15-supported ionic liquid-Pd (OAc) 2

JY Jung, A Taher, HJ Kim, WS Ahn, MJ Jin

Index: Jung, Ji-Young; Taher, Abu; Kim, Hyun-Jin; Ahn, Wha-Seung; Jin, Myung-Jong Synlett, 2009 , # 1 p. 39 - 42

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Citation Number: 9

Abstract

Abstract Palladium acetate was immobilized into the pores of modified SBA-15 with absorbed ionic liquid. The immobilized catalyst system was studied for Heck coupling. The catalyst exhibited high catalytic activity in the coupling of aryl iodides and activated aryl bromides with acrylates. Moreover, it could be recycled without significant loss of activity.