Journal of fluorine chemistry

Condensation of fluoroalkyl-containing 1, 3-dicarbonyl compounds with ethylenediamine

VI Saloutin, ZE Skryabina, YV Burgart

Index: Saloutin, V. I.; Skryabina, Z. E.; Burgart, Y. V. Journal of Fluorine Chemistry, 1992 , vol. 56, # 3 p. 325 - 334

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Citation Number: 7

Abstract

Abstract 2, 3-Dihydro-1H-1, 4-diazepines have been prepared by the direct interaction of fluoroalkylated 1, 3-diketones with ethylenediamine hydroperchlorate; similarly, 1, 2, 3, 4- tetrahydro-1, 4-diazepine-5-ones have been obtained from fluorinated 1, 3-keto esters. Under mild conditions, fluorinated copper (II) 1, 3-diketonates, and copper (II) and nickel (II) N, N′-ethylenebis (aminovinyl ketonates) were found to react with ethylenediamine to ...