The Journal of organic chemistry

Transition-Metal-Free Acid-Mediated Synthesis of Aryl Sulfides from Thiols and Thioethers

AM Wagner, MS Sanford

Index: Wagner, Anna M.; Sanford, Melanie S. Journal of Organic Chemistry, 2014 , vol. 79, # 5 p. 2263 - 2267

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Citation Number: 22

Abstract

One of the most common routes to aryl sulfides involves the transition-metal-catalyzed cross-coupling of aryl halides or pseudo-halides with thiols under basic conditions.(11-16) A number of base-mediated, transition-metal-free reactions for aryl sulfide synthesis have also been reported.(17-25) While these represent highly useful transformations, the vast majority of current synthetic methods for aryl sulfide synthesis require at least one of the following: ...

~50%

~65%

1073-72-9

4-Hydroxythioanisole

~90%

~56%

~56%

~20%

~56%

~85%

~78%

~79%

~36%

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