Preparation of optically pure propargylic and allylic alcohols from 2-(trimethylsilyl) vinyl sulfoxides as a chiral ethynyl anion synthon: Computational studies on …

S Nakamura, S Kusuda, K Kawamura…

Index: Reich, Hans J.; Willis, William W. Journal of the American Chemical Society, 1980 , vol. 102, # 18 p. 5967 - 5968

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Citation Number: 21

Abstract

... The Journal of Organic ... the lithium carbanion completely, which was then reacted with an aldehyde at the same temperature for 5 min giving good yields of the products 4a−j. The yields and the diastereomer ratios obtained in the reaction with benzaldehyde, acetaldehyde ...