Journal of organometallic chemistry

Convenient route to di-and triorganosilyl ethyl ethers and the corresponding di-and triorganosilanes

JM Tour, JA John, EB Stephens

Index: Tour, James M.; John, Jens A.; Stephens, Eric B. Journal of Organometallic Chemistry, 1992 , vol. 429, # 3 p. 301 - 310

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Citation Number: 10

Abstract

Abstract Tetraetboxysilane was treated with alkyl-and aryllithium reagents for the preparation of organosilyl ethyl ethers of the type R 3 SiOEt, R 2 R′ SiOEt, and R 2 Si (OEt) 2, that can be reduced to the organosilanes R 3 SiH, R 2 R′ SiH, and R 2 SiH 2, respectively. Compounds of the type RR′ R′ SiOEt cannot be cleanly formed. The reduction procedure involves treatment of the silyl alkoxy ethers with diisobutylaluminium ...