Tetrahedron

Functionalisation of saturated hydrocarbons. Part xvii. Reactivity of carbon-carbon double bonds

DHR Barton, KW Lee, W Mehl, N Ozbalik, L Zhang

Index: Barton, Derek H. R.; Lee, Kyu Wan; Mehl, Wolf; Ozbalik, Nubar; Zhang, Li Tetrahedron, 1990 , vol. 46, # 11 p. 3753 - 3768

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Citation Number: 36

Abstract

The Gif oxidation systems cleave methylidene olefins into the ketone or aldehyde and formaldehyde. This is considered to be a further manifestation of an Vfe oxenoid species. Similarly, more substituted olefins are oxidized to the corresponding unsaturated ketones ...