Synthesis

Palladium-Catalyzed Carbonylative Coupling of Iodonium Salts with Organostannanes under Aqueous Conditions: Synthesis of Unsymmetrical Vinyl and Aromatic …

SK Kang, PS Ho, SK Yoon, JCL Lee, KJ Lee

Index: Kang, Suk-Ku; Ho, Pil-Su; Yoon, Seok-Keun; Lee, Ju-Cheol; Lee, Kyung-Ju Synthesis, 1998 , # 6 p. 823 - 825

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Citation Number: 14

Abstract

Abstract: The palladium-catalyzed carbonylative coupling reaction of hypervalent iodonium salts with organostannanes was accomplished in the presence of PdCl2 (0.2 mol%) under atmospheric pressure of carbon monoxide at room temperature under aqueous conditions. Key words: palladium-catalyzed carbonylative coupling, hypervalent iodonium salts, organostannanes, unsymmetrical vinyl ketones, unsymmetrical aromatic ketones

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