Rhodium (III)??Catalyzed Dehydrogenative Heck Reaction of Salicylaldehydes

Z Shi, N Schröder, F Glorius

Index: Shi, Zhuangzhi; Schroeder, Nils; Glorius, Frank Angewandte Chemie - International Edition, 2012 , vol. 51, # 32 p. 8092 - 8096

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Citation Number: 86

Abstract

The transition-metal-catalyzed Mizoroki–Heck reaction is one of the most popular and powerful tools for CÀC bond formation and offers a straightforward approach for the construction of olefination products.[1] Three kinds of substrates are typically utilized as the coupling partner for the olefin in this reaction: aryl halides or pseudohalides, organometallic reagents, and non-preactivated (hetero) arenes. In terms of atom economy the third type of ...

 Related Synthetic Route
phenylene-ethylene Structure

292638-84-7

phenylene-ethylene

Salicylaldehyde Structure

90-02-8

Salicylaldehyde

~35%

FLAVANONE Structure

487-26-3

FLAVANONE

phenylene-ethylene Structure

292638-84-7

phenylene-ethylene

5-HYDROXY-2,2-DIMETHYL-2H-CHROMENE-6-CARBALDEHYDE Structure

54287-99-9

5-HYDROXY-2,2-D...

~56%

(2E)-1-(5-Hydroxy-2,2-dimethyl-2H-1-benzopyran-6-yl)-3-phenyl-2-propen-1-one Structure

31501-55-0

(2E)-1-(5-Hydro...

b-Resorcylaldehyde Structure

95-01-2

b-Resorcylaldehyde

~%

(2E)-1-(5-Hydroxy-2,2-dimethyl-2H-1-benzopyran-6-yl)-3-phenyl-2-propen-1-one Structure

31501-55-0

(2E)-1-(5-Hydro...

butyl acrylate Structure

141-32-2

butyl acrylate

Salicylaldehyde Structure

90-02-8

Salicylaldehyde

~77%

butyl 2-(3-oxo-1-benzofuran-2-ylidene)acetate Structure

65547-90-2

butyl 2-(3-oxo-...

3-Methyl-2-butenal Structure

107-86-8

3-Methyl-2-butenal

b-Resorcylaldehyde Structure

95-01-2

b-Resorcylaldehyde

~59%

5-HYDROXY-2,2-DIMETHYL-2H-CHROMENE-6-CARBALDEHYDE Structure

54287-99-9

5-HYDROXY-2,2-D...

phenylene-ethylene Structure

292638-84-7

phenylene-ethylene

Salicylaldehyde Structure

90-02-8

Salicylaldehyde

~67%

2-Propen-1-one,1-(2-hydroxyphenyl)-3-phenyl-, (2E)- Structure

888-12-0

2-Propen-1-one,...

phenylene-ethylene Structure

292638-84-7

phenylene-ethylene

[α,D]-o-hydroxybenzaldehyde Structure

71367-06-1

[α,D]-o-hydroxy...

~%

2-Propen-1-one,1-(2-hydroxyphenyl)-3-phenyl-, (2E)- Structure

888-12-0

2-Propen-1-one,...

ethene Structure

54509-73-8

ethene

2-Hydroxy-5-methylbenzaldehyde Structure

613-84-3

2-Hydroxy-5-met...

~28%

2'-Hydroxy-5'-methylpropiophenone Structure

938-45-4

2'-Hydroxy-5'-m...


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