The Journal of Organic Chemistry

Aryne reactions of polyhalobenzenes with alkenyl and alkynyl Grignard reagents

CJF Du, H Hart

Index: Du, Chi-Jen Frank; Hart, Harold Journal of Organic Chemistry, 1987 , vol. 52, # 19 p. 4311 - 4314

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Citation Number: 30

Abstract

Polyhalobenzenes react with alkenyl Grignard reagents to form from one to four new aryl- alkenyl bonds, depending on the particular polyhalobenzene used, in a single operation. Three types of reactions are involved in the mechanism: organometallic exchange, followed