Structural and mechanistic effects on the rates of ring-opening reactions in the 5-16-membered-ring region

G Cerichelli, G Illuminati, C Lillocci

Index: Cerichelli, Giorgio; Illuminati, Gabriello; Lillocci, Claudio Journal of Organic Chemistry, 1980 , vol. 45, # 20 p. 3952 - 3957

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Citation Number: 26

Abstract

Results The reactions were carried out in methanolic solution, 0.1 M in methoxide ion and 0.05 M in the ammonium salt, and were followed to complete conversion at 130 “C in sealed ampules. The overall reaction rates were measured by the acid-base potentiometric microtitration of the total amine product formed. The product analyses were carried out by the gas chromatographic method on reaction mixtures obtained under the conditions of ...