N, N-bis-(1-aryl-3-methyltriazen-3-ylmethyl) methylamines (1, 9-diaryl-3, 5, 7-trimethyl-1, 2, 3, 5, 7, 8, 9-hepta-azanona-1, 8-dienes): novel coupling products from the …

RJ Lafrance, Y Tang, K Vaughan…

Index: Lafrance, Ronald J.; Tang, York; Vaughan, Keith; Hooper Donald L. Journal of the Chemical Society, Chemical Communications, 1983 , # 13 p. 721 - 722

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Citation Number: 3

Abstract

The reaction of arenediazonium ions with aqueous formaldehyde-methylamine solutions affords mixtures of the 3-hydroxymethyltriazenes, ArN=NN (Me)CH,OH, and the previously unreported bis(triazenylmethy1)methyl- ami nes, Ar NN N ( Me) CH 2N ( Me) C H 2N ( Me) N=NAr. ... Reaction of formaldehyde-methylamine mixtures with arene- ... Julliard et a/.3 are in fact examples of (2), a novel class of ... XC,H,-N=NN( Me)CH,OH ... [p-XC,H4-N=NN( Me)CH, ],NMe (1)