Chemistry Letters

Electroreductive Acylation of Benzyl Chlorides with Acid Anhydrides. Stereoselective Formation of (E)-Enol Esters from Benzyl Alkyl Ketones.

I Nishiguchi, T Oki, T Hirashima, J Shiokawa

Index: Nishiguchi, Ikuzo; Oki, Tsuneo; Hirashima, Tsuneaki; Shiokawa, Jiro Chemistry Letters, 1991 , p. 2005 - 2008

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Citation Number: 2

Abstract

2006 Chemistry Letters, 1991 li ead – plate cath odeandacarb on –rod an o de were at ta che d . To a cath o 1 y te was ad de d 2. 53 g (0.02 mol) of benzy 1 ch 1 or i de (1a) and 20. 4 g (0.20 mol) of ac et ic anhydrid e (2a) . The mixture was e1 ectro 1 y ed with stir ring at ro on t en per a ture under c on stantcu rr en t con dit ion ( curr en t - den sity : 1 5–1 O mA/cm* ) un til 4.0 F/mol of electricity has been charged. The usual work-up of the cathol y te and the dist i ...