Activation and stabilization of small molecules by a chelating triphosphine-rhodium (I) complex. Correlation of the chemistry with the structures of chlorobis (3-diphenyl …

TE Nappier, DW Meek, RM Kirchner…

Index: Nappier et al. Journal of the American Chemical Society, 1973 , vol. 95, p. 4194,4195, 4204 Full Text View citing articles Show Details Nappier, T. E.; Meek, D. W. Journal of the American Chemical Society, 1972 , vol. 94, p. 306 - 307 Full Text View citing articles Show Details Gmelin Handbook: Rh: SVol.B3, 4.26.3.1, page 188 - 191

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Citation Number: 72

Abstract

Abstract: The tridentate ligand C~ H, P [CHCHZCH~ P (C, H,)~~~, L, forms RhLX complexes (X= C1, Br, I), which are dissociatively stable in nonaqueous solvents. The chloride complex, RhLCl, reacts readily with a variety of small molecules to form five-coordinate, nonionic derivatives, RhLCl. A, where A= BF,, CO, SOz, and 02. The S2 adduct, RhLC1. S2, was prepared by treating RhLCl with SS in benzene. Cationic complexes of RhLCl were made ...