… , characterization, and catalytic activity of Rh (I) complexes with (S)-BINAPO, an axially chiral inducer capable of hemilabile P, O-heterobidentate coordination

S Gladiali, S Medici, T Kégl, L Kollàr

Index: Gladiali, Serafino; Medici, Serenella; Kegl, Tamas; Kollar, Laszlo Monatshefte fur Chemie, 2000 , vol. 131, # 12 p. 1351 - 1361

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Citation Number: 24

Abstract

Summary. The reaction of dinuclear rhodium (I) derivatives of the formula [Rh (DIOL) X] 2 with the axially chiral phosphinyl phosphane 2-(diphenylphosphinyl)-2′- (diphenylphosphanyl)-1, 1′-binaphthalene ((S)-BINAPO, 1) leads to the formation of cationic complexes [(BINAPO) Rh (DIOL)]+ where the ligand (S)-BINAPO consistently displays a P, O-chelate coordination which is mantained even in solvents of fair polarity. ...