The Journal of Organic Chemistry

Synthesis and Alkaline Degradation of the Arenesulfonyl Derivatives of α-Menaphthyl-and 1, 1-Di-α-menaphthylhydrazine1

LA Carpino

Index: Carpino,L.A. Journal of Organic Chemistry, 1965 , vol. 30, # 2 p. 321 - 323

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Citation Number: 13

Abstract

Attempts to prepare 1, l-di-a-menaphthylhydrazine by alkylation of t-butyl carbazate by means 6f l-chloromethylnaphthalene gave only the monoalkylated product I11 which wm characterized by cleavage to a-menaphthylhydrazine, tosylation of which gave 1-a- menaphthyl-1-p-tluenesulfonhydrazide(IV). The structure of IV waa established by an alternate synthesis which involved amination of Na-menaphthyl-p-toluenesulfonamide by ...