Derivatives of tetrahedral boronic acids

M Biedrzycki, WH Scouten, Z Biedrzycka

Index: Biedrzycki, Marek; Scoutan, William H.; Biedrzycka, Zenobia Journal of Organometallic Chemistry, 1992 , vol. 431, # 3 p. 255 - 270

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Citation Number: 24

Abstract

Abstract A series of aliphatic and benzylic bifunctional boronate esters have been prepared as potential ligands for affinity chromatography. α-Acetamido, picolino, thioureido and acetamidino boronates have the hetero atom coordinated with the boron, creating a tetrahedral structure. The 1 H, 13 C and 11 B NMR for these compounds confirm the structure, as well as the hetero atom—boron coordination, and show that the bonding of ...