Activation of CO and CN Bonds in Allylic Alcohols and Amines by Palladium Complexes Promoted by CO2. Synthetic Applications to Allylation of Nucleophiles, …

M Sakamoto, I Shimizu, A Yamamoto

Index: Sakamoto, Masato; Shimizu, Isao; Yamamoto, Akio Bulletin of the Chemical Society of Japan, 1996 , vol. 69, # 4 p. 1065 - 1078

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Citation Number: 83

Abstract

The direct activation of the C–O bonds in allylic alcohols catalyzed by palladium complexes has been accelerated by carrying out the reactions under CO 2. On reaction with diethylamine, allyl alcohol can be converted into N, N-diethylallylamine in the presence of palladium complexes at room temperature under normal pressure of carbon dioxide. Allylation of various carbon nucleophiles such as β-keto esters and β-diketones can be ...