Tetrahedron letters

Deoxygenation of sulfoxides and selenoxides with nickel boride

JM Khurana, A Ray, S Singh

Index: Khurana, Jitender M.; Ray, Abhijit; Singh, Sarika Tetrahedron Letters, 1998 , vol. 39, # 22 p. 3829 - 3832

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Citation Number: 47

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The deoxygenations of a variety of acyclic sulfoxides and selenoxides have been reported with nickel boride in THF at 0–5°C in nearly quantitative yields. The deoxygenations are proposed to proceed by an oxidative-addition and reductive-elimination mechanism.

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