Journal of Organometallic Chemistry

Cyclo-hydrosilylation: A novel route to siloxetanes and silanones

TH Lane, CL Frye

Index: Lane,T.H.; Frye,C.L. Journal of Organometallic Chemistry, 1979 , vol. 172, p. 213 - 221

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Abstract

Abstract A novel and convenient method for the apparent liquid phase generation of dimethylsilanone, Me 2 Si O (D 1), based on readily obtainable reactants and employing conventional temperatures (50–150) is reported herein. Platinum catalyzed hydrosilylation of vinyldimethylcaarbinoxydimethylsilane (I) appears to proceed by an exclusively intramolecular path to produce not only the expected 5-membered heterocyclic, 1, 1, 3, 3- ...