Journal of organometallic chemistry

Efficient formation and cleavage of disilanes by potassium-graphite. Silylation with silyl metal reagents

A Fürstner, H Weidmann

Index: Fuerstner, Alois; Weidmann, Hans Journal of Organometallic Chemistry, 1988 , vol. 354, p. 15 - 22

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Citation Number: 55

Abstract

Abstract Potassium-graphite laminate (C 8 K) very rapidly forms disilanes from chlorosilanes and then rapidly cleaves the disilanes to give silyl potassium reagents which can be converted into potassium silyl cuprates,-manganates, and-vanadates that are useful for various nucleophilic substitution and addition reactions.

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