Abstract: N-{[(4-bromophenyl) amino] carbonothioyl} benzamide was synthesized and characterized by IR,^ 1H-and^{13} C-NMR, mass spectrometry, and elemental analysis. The crystal structure was determined from single crystal X-ray diffraction data. It crystallizes in monoclinic space group P2_1/n with unit cell dimensions a= 13.822 (3) Å, b= 5.927 (2) Å, c= 16.642 (3) Å, and\ beta= 103.963 (3). There is a strong intramolecular hydrogen bond of ...