Mild oxidative functionalization of alkanes and alcohols catalyzed by new mono-and dicopper (II) aminopolyalcoholates

AM Kirillov, MV Kirillova, LS Shul'pina, PJ Figiel…

Index: Kirillov, Alexander M.; Kirillova, Marina V.; Shul'Pina, Lidia S.; Figiel, Pawel J.; Gruenwald, Katrin R.; Guedes Da Silva, M. Fatima C.; Haukka, Matti; Pombeiro, Armando J.L.; Shul'Pin, Georgiy B. Journal of Molecular Catalysis A: Chemical, 2011 , vol. 350, # 1-2 p. 26 - 34

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Citation Number: 51

Abstract

The new mono-and dicopper (II) complexes [Cu (H3L1)(NCS)](1) and [Cu2 (μ-HL2) 2 (NCS) 2](2) were easily self-assembled from Cu (CH3COO) 2· H2O, NaNCS, NaOH and N, N, N′, N′-tetrakis (2-hydroxyethyl) ethylenediamine (H4L1) or N-ethyldiethanolamine (H2L2), respectively. They were fully characterized by IR spectroscopy, ESI-MS (±), elemental and single-crystal X-ray diffraction analyses, and applied as homogeneous catalysts for (i) the ...