The Journal of organic chemistry

Benzotriazole-mediated [2, 3]-Wittig rearrangement. General and Stereocontrolled syntheses of homoallyl alcohols and β, γ-unsaturated ketones

AR Katritzky, H Wu, L Xie

Index: Marceau, P.; Gautreau, L.; Beguin, F.; Guillaumet, G. Journal of Organometallic Chemistry, 1991 , vol. 403, # 1.2 p. 21 - 27

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Citation Number: 18

Abstract

... an allyl alcohol, and an aromatic aldehyde in the presence of molecular sieves and p-toluenesulfonic acid ... General Procedure for the Preparation of Secondary Homoallyl Alcohols 16a−f. To a solution of the ... 3,3-Dimethyl-1-octen-4-ol (16a): colorless oil, yield (0.23 g, 87%); 1 ...

~83%

~85%

~64%

~61%

~0%

~0%

~80%

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