Russian chemical bulletin

Chemo-and regioselective nitration of geranylacetone by NaNO2/AcOH. Synthesis of 6, 10-dimethyl-9-methyleneundec-5E-en-2-one

AV Stepanov, VV Veselovsky

Index: Stepanov; Veselovsky Russian Chemical Bulletin, 1999 , vol. 48, # 7 p. 1287 - 1290

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Abstract

Abstract Treatment of geranylacetone with NaNO 2 in AcOH affords 6, 10-dimethyl-9- nitroundeca-5 E, 10-dien-2-one as the major product. This product was used to synthesize 6, 10-dimethyl-9-methyleneundec-5 E-en-2-one, a component of the essential oil from the