Tetrahedron

Materials chemistry approach to anion-sensor design

P Anzenbacher, K Jursikova, D Aldakov, M Marquez…

Index: Anzenbacher Jr., Pavel; Jursikova, Karolina; Aldakov, Dmitry; Marquez, Manuel; Pohl, Radek Tetrahedron, 2004 , vol. 60, # 49 p. 11163 - 11168

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Citation Number: 40

Abstract

A new approach to sensing of aqueous phosphate-related anions based on chromogenic conductive polymers is demonstrated. The anion-sensor affinity can be adjusted by externally applied voltage. Introduction of p-doping to the polymers results in augmented anion sensitivity, which is ascribed to the effect of synergy between low-level p-doping in a polythiophene polymer and hydrogen bonding. The chromogenic conductive polymer ...