Comparative Syntheses of Arylamine Monomer with Styrylpyridyl Photo-Crosslinker of Polyarylamine for OLED Hole-Injection Material

HJ Choi, MG Song, YH Sim, HK Bae…

Index: Choi, Heung-Jin; Song, Moo-Gon; Sim, Youn-Hee; Bae, Heung-Kwon; Kim, Jin-Woo; Park, Lee Soon Molecular Crystals and Liquid Crystals, 2010 , vol. 531, p. 47 - 54

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Abstract

A new arylamine monomer with photo-crosslinkable styrylpyridinyl moiety of conjugated polyarylamine for OLED hole injection material was synthesized through two synthetic routes, BOC-amine protection/deprotection and nitro group reduction methods. Both synthetic routes yielded practically pure amine product by standard aqueous workup and crystallization in 61% overall yield from pyridinylvinylphenol 2. Their reaction efficiencies ...