Reductive Cleavage of the C sp 2 C sp 3 Bond of Secondary Benzyl Alcohols: Rhodium Catalysis Directed by N??Containing Groups

…, ZQ Lei, Y Li, WH Ye, LS Zhang, J Sun…

Index: Chen, Kang; Li, Hu; Lei, Zhi-Quan; Li, Yang; Ye, Wen-He; Zhang, Li-Sheng; Sun, Jian; Shi, Zhang-Jie Angewandte Chemie - International Edition, 2012 , vol. 51, # 39 p. 9851 - 9855

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Citation Number: 27

Abstract

Oxidative coupling of two nucleophiles to construct a CÀC bond (Scheme1) is gradually becoming a prestigious and powerful method relative to the traditional cross-coupling reactions.[1] Specifically, recent developments in cross-dehydrogenative coupling/arylation made such a transformation more popular and “greener” and produces valuable compounds by avoiding the preactivation of easily available and inexpensive chemicals.[2] In contrast, ...

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