Russian journal of organic chemistry

Alcoholysis of 3-alkoxy-2-cyclohexene-1-thiones

LV Timokhina

Index: Timokhina Russian Journal of Organic Chemistry, 2009 , vol. 45, # 11 p. 1723 - 1724

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Abstract

3-Alkoxy-2-cyclohexene-1-thiones Ia and IIa that we formerly synthesized are exclusively reactive compounds [1]. They especially readily react with nucleophilic reagents at the C– Oalk bond (aminolysis, thiolysis) due to the conjugation of the alkoxy group with the thiocarbonyl fragment [1, 2]. The oxygen analogs of thiones do not enter into such reactions or react in far more stringent conditions [3]. One more proof of the high lability of the ...