Free radical chemistry. Part 10. 1 Addition of acyclic and cyclic alkanes to hexafluoropropene

…, MP Greenhall, AM Kenwright, AS Batsanov…

Index: Chambers, Richard D.; Fuss, Robert W.; Spink, Robert C. H.; Greenhall, Martin P.; Kenwright, Alan M.; Batsanov, Andrei S.; Howard, Judith A. K. Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 10 p. 1623 - 1638

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Abstract

γ-Ray or peroxide initiated reactions of acyclic and cyclic alkanes with hexafluoropropene are described. A variety of perfluorocarbons and polyfluorinated alkenes, di-enes and a tetra- ene were synthesised from these polyfluoroalkylated alkanes. Elimination of hydrogen fluoride gives fluorinated alkenes, with unusual kinetic control of product formation and further fluorinations gave novel perfluorocarbons. X-Ray crystallography established ...