Copper??Catalyzed Cross??Coupling Interrupted by an Opportunistic Smiles Rearrangement: An Efficient Domino Approach to Dibenzoxazepinones

…, TE Hurst, V Snieckus

Index: Kitching, Matthew O.; Hurst, Timothy E.; Snieckus, Victor Angewandte Chemie - International Edition, 2012 , vol. 51, # 12 p. 2925 - 2929

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Citation Number: 36

Abstract

The construction of CÀO and CÀN bonds by palladium-and copper-mediated cross-coupling approaches has undergone a renaissance in the last decade.[1] Although the utility of these coupling approaches to effect a single-bond construction event has now been established, the quest to improve efficiency has driven the further exploration of one-pot procedures for effecting multiple transformations, often by a domino [2] approach. Success in this area ...