N-nitrosamines from the reaction of N-chlorodialkylamines with sodium nitrite

M Nakajima, JC Warner, JP Anselme

Index: Nakajima, Masayuki; Warner, John C.; Anselme, Jean-Pierre Journal of the Chemical Society, Chemical Communications, 1984 , # 7 p. 451 - 452

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Abstract

The reaction of N-chlorodialkylamines with sodium nitrite leads to the corresponding N-nitrosamines in excellent yields. ... HO (PhCH,),NCl+ NO2- - PhCH=NCH2Ph 2PhCHO ... Over the last twenty five years, the generation and trans- formations of N-nitrosamines have become topics of major ... Scheme 1 yield of (2) increased with a concomitant decrease in the amount of the unknown solid. The generation of benzaldehyde was rationalized in terms of elimination of the ...