Palladium??Catalysed Cross??Coupling Reactions of Triorganoindium Reagents with Alkenyl Halides

R Riveiros, L Saya, J Perez Sestelo…

Index: Riveiros, Ricardo; Saya, Lucia; Sestelo, Jose Perez; Sarandeses, Luis A. European Journal of Organic Chemistry, 2008 , # 11 p. 1959 - 1966

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Abstract

Abstract The regio-and stereoselectivity of the palladium-catalysed cross-coupling reactions of indium organometallics withstereodefined 1-haloalkenes and 1, 1-dihaloalkenes have been studied. Triorganoindium reagents (R 3 In; R= alkyl, alkenyl, aryl and alkynyl) can be stereospecifically coupled with stereodefined alkenyl iodides in good yields and short reaction times under palladium catalysis. Additionally, the palladium-catalysed cross- ...