Abstract Some alkylnaphthalene and alkylphenanthrene sulfonates were synthesized by means of a Wurtz–Fittig reaction. The HLB values for the prepared compounds were calculated, and the basic properties were studied in water at different temperatures, namely, 25, 35 and 45° C. Through surface tension measurements, the following values were determined: the critical micelle concentration (CMC) and the surface tension at the CMC (γ ...