Reaction of 1, 1-dichloroethane with tellurium in the system hydrazine hydrate-potassium hydroxide

EP Levanova, VA Grabel'nykh, AV Kolesnikov…

Index: Levanova; Grabel'nykh; Kolesnikov; Klyba; Zhanchipova; Albanov; Russavskaya; Korchevin Russian Journal of Organic Chemistry, 2009 , vol. 45, # 7 p. 988 - 992

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Citation Number: 2

Abstract

Abstract The reaction of 1, 1-dichloroethane with tellurium in the system hydrazine hydrate- potassium hydroxide gave ethyltellanyl derivatives as a result of replacement of one chlorine atom in the substrate by tellurium, and of the other, by hydrogen. Probable mechanisms of reduction of the C-Cl bond and mass spectra of the products were considered. The mass spectra of ditelluroacetals revealed unusual rearrangement of the molecular ion, leading ...