Monohydroxamic acids and bridging dihydroxamic acids as chelators to ruthenium (III) and as nitric oxide donors: syntheses, speciation studies and nitric oxide …

…, K Krot, J Comiskey, KB Nolan, CJ Marmion

Index: Griffith, Darren; Krot, Krystyna; Comiskey, Jedd; Nolan, Kevin B.; Marmion, Celine J. Dalton Transactions, 2008 , # 1 p. 137 - 147

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Citation Number: 14

Abstract

The synthesis and spectroscopic characterisation of novel mononuclear RuIII (edta)(hydroxamato) complexes of general formula [Ru (H2edta)(monoha)](where monoha= 3-or 4-NH2, 2-, 3-or 4-Cl and 3-Me-phenylhydroxamato), as well as the first example of a RuIII-N-aryl aromatic hydroxamate,[Ru (H2edta)(N-Me-bha)]· H2O (N-Me-bha= N- methylbenzohydroxamato) are reported. Three dinuclear RuIII complexes with bridging ...