Dalton Transactions

Negishi cross-coupling reaction catalyzed by an aliphatic, phosphine based pincer complex of palladium. biaryl formation via cationic pincer-type Pd IV intermediates

R Gerber, O Blacque, CM Frech

Index: Dalton Transactions, , vol. 40, # 35 p. 8996 - 9003

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Citation Number: 28

Abstract

... DOI: 10.1039/C1DT10398A (Paper) Dalton Trans., 2011, 40, 8996-9003 ... The aliphatic, phosphine-based pincer complex [(C 10 H 13 -1,3-(CH 2 P(Cy 2 ) 2 )Pd(Cl)] (1) is a highly active Negishi catalyst, enable to quantitatively couple various electronically activated, non ...