Bis (. MU.-iodo) bis [(-)-sparteine] dicopper: A Versatile Catalyst for Direct O-Arylation and O-Alkylation of Phenols and Aliphatic Alcohols with Haloarenes

P Satyanarayana, H Maheswaran, ML Kantam…

Index: Satyanarayana, Ponnam; Maheswaran, Hariharasarma; Kantam, Mannepalli Lakshmi; Bhargava, Suresh Bulletin of the Chemical Society of Japan, 2011 , vol. 84, # 7 p. 788 - 790

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Citation Number: 4

Abstract

The easy to prepare dimeric bis (μ-iodo) bis [(−)-sparteine] dicopper ([CuI {(−)-spa}] 2 complex) is shown to be versatile catalyst for O-arylation and O-alkylation with various aryl halides with phenols and aliphatic alcohols respectively, including less reactive aryl chlorides, such as chlorobenzene under mild conditions.

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