Journal of Organometallic Chemistry

Phenyl (trimethylsilyl) ketene. Some ketene reactions with diazomethane

WT Brady, TC Cheng

Index: Brady,W.T.; Cheng,T.C. Journal of Organometallic Chemistry, 1977 , vol. 137, p. 287 - 292

Full Text: HTML

Citation Number: 0

Abstract

Abstract Phenyl (trimethylsilyl) ketene was prepared by the zinc dehalogenation of phenyl (trimethylsilyl) bromoacetyl chloride. This ketene parallels tirmethylsilylketene in stabibility and lack of reactivity in cycloaddition reactions. The reaction of phenyl (ethyl)-, phenyl (trimethylsilyl)-and trimethylsilylketenes with diazomethane at− 78 C is described. Only the 21 cycloadducts, the cyclobutanones, could be isolated.

Iron salt, a cheap, highly efficient and environment-friendl...

[Yu, Lei; Ren, Lingfeng; Yi, Rong; Wu, Yulan; Chen, Tian; Guo, Rong Journal of Organometallic Chemistry, 2011 , vol. 696, # 10 p. 2228 - 2233]

The first example of asymmetric dihydroxylation of cycloprop...

[Nemoto, Hideo; Miyata, Junji; Hakamata, Hideki; Fukumoto, Keiichiro Tetrahedron Letters, 1995 , vol. 36, # 7 p. 1055 - 1058]

Ring-Enlargement of Dimethylaminopropenoyl Cyclopropanes: An...

[Nakajima, Tadashi; Segi, Masahito; Mituoka, Takeshi; Fukute, Yasuyuki; Honda, Mitsunori; Naitou, Kaneyuki Tetrahedron Letters, 1995 , vol. 36, # 10 p. 1667 - 1670]

First synthesis of (1S, 2S)-and (1R, 2R)-1-amino-2-isopropyl...

[Truong, Molika; Lecornue, Frederic; Fadel, Antoine Tetrahedron Asymmetry, 2003 , vol. 14, # 8 p. 1063 - 1072]

Vinyl cations. 41. Influence of 4-aryl and 4-alkyl substitue...

[Collins, Clair J.; Hanack, Michael; Stutz, Herbert; Auchter, Gerhard; Schoberth, Winfried Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5260 - 5268]