Journal of organometallic chemistry

An efficient catalyst for the synthesis of ortho-substituted biaryls by the Suzuki cross-coupling: Triphenylphosphine adduct of cyclopalladated ferrocenylimine

H Li, Y Wu, W Yan

Index: Li, Hong; Wu, Yangjie; Yan, Weibo Journal of Organometallic Chemistry, 2006 , vol. 691, p. 5688 - 5696

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Citation Number: 12

Abstract

The air and moisture stable triphenylphosphine adduct of cyclopalladated ferrocenylimine 2 has been successfully used in palladium-catalyzed Suzuki cross-coupling for the synthesis of ortho-substituted biaryls in air. In the presence of 0.05 mol% of 2 as catalyst and 3