Journal of the American Chemical Society

Carbon-carbon bond formation via the reaction of trialkylallylstannanes with organic halides

GE Keck, JB Yates

Index: Keck, Gary E.; Yates, John B. Journal of the American Chemical Society, 1982 , vol. 104, # 21 p. 5829 - 5831

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Citation Number: 246

Abstract

In connection with ongoing synthetic studies in our laboratories, we required a method for the replacement of halogen by an allyl moiety in substrates such as bromolactone 1 (Table I). Very few methods compatible with such substrates are known, since conversion of 1 to an organometallic derivative, or reaction of such substrates with organometallic derivatives, is frustrated by an obviously facile reductive elimination possibility. Palladiumcatalyzed ...