Electrochemical generation of cationic Pd catalysts and application to Pd/TEMPO double-mediatory electrooxidative Wacker-type reactions

…, E Nakamoto, K Yoshida, H Tanaka

Index: Tanaka, Hideo; Kubota, Jun; Itogawa, Shin-Ji; Ido, Toru; Kuroboshi, Manabu; Shimamura, Kaoru; Uchida, Tetsuya Synlett, 2003 , # 7 p. 951 - 954

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Citation Number: 44

Abstract

We have developed an electrooxidative method for generating cationic palladium complexes [Pd (CH3CN) 4][X] 2 (X= BF4, PF6, and ClO4) from Pd (OAc) 2 and several electrolytes bearing X groups in CH3CN. The system could be integrated into an